In addition, tests were performed to evaluate stress corrosion cracking of sensitized type 304 stainless steel and postweld heattreated astm a336f1, a302b, and a106b carbon and low alloy steels in a solution to be used to remove residual metallic copper from the dresden 1 primary system surfaces following the chemical cleaning. The material used is 304 aisi stainless steel sheets of 3. Stress corrosion cracking scc is the cracking induced from the combined influence of tensile stress and a corrosive environment. Percentage elongation and reduction in crosssectional area were used to investigate the scc of the steel. It was concluded by an electrochemical experiment 3,4 with solutions consisting of 10 m and up to 2 m and at temperatures from 60 to 95 c, that lowcarbon steels may be susceptible to caustic stress corrosion cracking cscc. Highperformance alloys for resistance to aqueous corrosion. Caustic stress corrosion cracking, also referred to as caustic embrittlement, is a form of degradation that is caused when a component operates in a caustic environment. Caustic stress corrosion cracking of 304 ss incinerator. However, some corrosion and stress corrosion cracking scc of dsss have been reported in different pulp mill environments employing caustic solutions. This damage mechanism primarily affects standard and high carbon stainless steels, but low carbon and chemically stabilized stainless steels may also be vulnerable under certain conditions.
However, subtle changes in stream composition or conditions often can profoundly affect corrosion rate and even foster a different corrosion mechanism. Caustic service material selection corrosion engineering. Duplex stainless steels dss with roughly equal amount of austenite and ferrite phases are being used in industries such as petrochemical and pulp and paper mills. Chloride stress corrosion cracking clscc is a type of stress corrosion cracking scc and is one of the most well known forms of scc in the refining and chemical processing industries. Used when there is a risk of localised corrosion only if crevices are present. Duplex stainless steels dsss have generally performed very well in caustic environments.
It is one of the most prevalent afflictions in the industry and one of many environmental cracking mechanisms that typically occur in carbon steel equipment, but it can also afflict low alloy and austenitic stainless steel equipment. Caustic stress corrosion cracking, also referred to as caustic embrittlement, is a form of degradation that is caused when a component operates in a caustic environment it is one of the most prevalent afflictions in the industry and one of many environmental cracking mechanisms that typically occur in carbon steel equipment, but it can also afflict low alloy and austenitic stainless steel. Aug 01, 2018 caustic cracking is a form of stress corrosion cracking most frequently encountered in carbon steels or ironchromiumnickel alloys that are exposed to concentrated hydroxide solutions at temperatures of 482f 250c. The mechanism is similar to that of chloride stress corrosion. Mild steels steels with low carbon and low alloy content and stainless steels will.
The purpose of this bulletin is to request addressees to identify, disassemble and inspect certain types of swing check valves which may contain type 410 stainless steel ss bolting material. Chloride stress corrosion cracking scc of type 304 and 304l austenitic stainless steels ss was studied by a constant load method in air at a temperature of 353k with relative humidity rh of 35%. Type 304l stainless steel is suitable as a material of construction for screens, blank plates, central pipe, internal cone, and. Yes yes yes mechanisms of corrosion in digesters stress corrosion cracking of carbon steel caustic stress corrosion cracking scc is the most serious form of corrosion that can occur in a continuous digester and has resulted in the catastrophic failure of a continuous digester. Zheng and bogaerts 6 have attributed scc of austenitic stainless steels in hot caustic solutions to the breakdown of the primary passivation and formation of secondary passivation. Pitting corrosion evaluation of austenitic stainless steel. Stress corrosion cracking sandvik materials technology. Results are reported for corrosion fatigue of type 304 stainless steel in boiling 140 c 17. Stress corrosion cracking scc is the formation and growth of crack through materials subjected to tensile stress and a specific corrosive medium. Caustic corrosion is a type of corrosion that occurs in metal equipment e. Corrosion behavior of inconel 625 heanjia super metals co. Caustic stress corrosion cracking of inconel600, incoloy800, and type 304. Chloride stress corrosion cracking scc of type 304 and 304l austenitic stainless steels ss was studied by a constant load method in air at a temperature of 353 k with relative humidity rh of.
This process involves accelerated corrosion along a path of higher than normal corrosion susceptibility, with the bulk of the material typically being passive. Endgrain corrosion of stainless steel can occur at the slots in the screens. Mar 04, 2020 corrosion developed after 4 weeks in the 304 and 304l specimens, and after 32 weeks in the 316l specimen. Analysis, interestingly, revealed that the observed caustic stress corrosion cracking cscc was not directly related to process parameters. Stress corrosion cracking this refers to the cracking caused by the simultaneous presence of tensile stress and a specific corrosive medium. The following conclusions can be drawn on the studies undertaken on ssc of type 304 austenitic stainless steel in dilute h 2 so 4 and nacl. Stainless steels are more resistant to general corrosion compared with carbon steel. This paper presents the influence of h 2so 4 and nacl concentrations on the corrosion mode of aisi 304 stainless steel in h 2so 4nacl aqueous solutions. The stress corrosion cracking scc of a commercial austenitic stainless steel type 304 was investigated as functions of chloride concentration, chromate concentration and test temperature under a constant applied stress condition in 0. T2 influences of h2so4 and nacl concentrations on stress. Specimens, of the smooth round bar type, were cycled sinusoidally at 1. The useful safe limit of carbon steel is approximately 150 o f65 o c, both with regard to caustic stress corrosion cracking cscc and corrosion. Caustic stress corrosion cracking of 304 ss incinerator material.
Piping ss 304 or 316 ss weld material nozzle butter safe end butter 308 ss or 308l ss 309308308l ss none. A lot depends on what kind of service the parts will see. It can be detrimental to austenitic stainless steels, one of the main reasons these steels are not considered a cureall for corrosion problems. Oct 15, 2017 caustic corrosion is a type of corrosion that occurs in metal equipment e. Specialized corrosion doehdbk1015193 corrosion ch02 rev. Stress corrosion cracking of 304l stainless steel in sodium. This material has good corrosion resistance due to the. Atmospheric stress corrosion cracking susceptibility of. Chloride stress corrosion cracking inspectioneering. Stainless steels types 304 and 316 can be considered resistant below 80 degc, up to the limit of solubility.
Chlorides simulating sea salt particles were put on the gage section of. Chloride stress corrosion cracking clscc is one the most common reasons why. A corrosive medium especially chloridebearing or hydrogensulphide h 2 s media. Caustic stress corrosion cracking scc is the most serious form of corrosion that can occur in a continuous digester. Relative corrosion resistance of standard stainless steel. Relative corrosion resistance of standard stainless steel grades for different environments acids hydrochloric acid stainless steel is generally not recommended except when solutions are very dilute and at room temperature pitting may occur. The resistance of austenitic stainless steel type 304 to pitting corrosion was studied in solutions of sulphuric acid 2m and 5 m with and without sodium chloride addition by linear polarization technique. The alloys comprising of 42 45% nickel will not be attacked in this. Austenitic stainless steels suffer from scc in chlorides, caustic, and polythionic acid. Corrosion developed after 4 weeks in the 304 and 304l specimens, and after 32 weeks in the 316l specimen. Caustic stress corrosion cracking inspectioneering. Stress corrosion cracking is a major issue for rcs. Effect of heat treatment on corrosion and stress corrosion.
Choosing the right materials of construction for process hardware and equipment is crucial for achieving desired service life. Nace international corrosion conference and expo corrosion refinery caustic injection systems. Stresscracking agents in process streams are not the only cause of scc. This suggests that the alloy composition plays a role in stress corrosion cracking susceptibility. Chlorides simulating sea salt particles were put on the gage section of the ss as droplets of synthetic sea water. Studies have shown that the corrosion and scc susceptibility of dsss depend on the alloy composition and microstructure of the steel. This standard recommended practice is intended to provide guidance to those designing, fabricating, andor maintaining carbon steel equipment and piping that is exposed to caustic environments. Depending on how low the c is in the l sss, you can perform a decent stressrelief wo sensitizing it. Babakr, abdul aziz almeshari, and samuel thomas, sabic stcj. The next line of defence in controlling stress corrosion cracking is testing to be sure that materials are safe on a batchbybatch basis.
Stress corrosion cracking of a monel 400 tube article pdf available in journal of failure analysis and prevention 46. Corrosion fatigue and stress corrosion cracking of type 304. Chloride induced stress corrosion cracking of type 304 and. Alloy 600 is employed in the fabrication of steam generator tubes in the nuclear power plants. Stress corrosion cracking scc sandvik materials technology. The forms of corrosion taken into consideration here are pitting and stress corrosion cracking. If the type 410 ss bolting material is of sufficiently high hardness that it is susceptible to stress corrosion cracking scc, or has failed. Nickel company, and type 304 stainless steel in caustic solutions. It is used in metal degreasing and cleaning processes in a wide range of industry applications. The evaporator recycle streams contain waste in a chemistry and temperature regime that may be outside of the current waste tank corrosion control program, which imposes temperature limits to mitigate caustic stress corrosion cracking cscc. Chloride stress corrosion cracking in austenitic stainless steel. Alloy 400 n04400 and alloy 600 n06600 also have excellent stress corrosion resistance.
Corrosion of carbon and stainless steels in flue gases from. Rp04032003 avoiding caustic stress corrosion cracking of carbon steel refinery equipment and piping. This new second edition serves as a goto reference on the complex subject of stress corrosion cracking scc, offering information to help metallurgists, materials scientists, and designers determine whether scc will be an issue for their design or application. It is one of the biggest groups in the family of nickel alloys that include alloy 600, alloy 825, alloy 800 and hastelloy g30. The effect of shot peening on the stress corrosion. In addition, tests were performed to evaluate stress corrosion cracking of sensitized type304 stainless steel and postweld heattreated astm a336f1, a302b, and a106b carbon and low alloy steels in a solution to be used to remove residual metallic copper from the dresden 1 primary system surfaces following the chemical cleaning. It is a broadly studied material for its immunity in stress corrosion cracking in.
These alloys can however suffer from caustic stress corrosion cracking at caustic concentrations above 70% at temperatures above 290crmo c 550f. This due to high concentration of the caustic soda added to the boiler water to control ph ph 9. Corrosion behavior of inconel 625 heanjia super metals. The stress corrosion cracking behavior in caustic solutions 200 gl sodium hydroxide, 10 gl sodium chloride of three austenitic 18cr10ni2. Stresscorrosion cracking of a monel 400 tube article pdf available in journal of failure analysis and prevention 46. Residual tensile stresses from welding have been the cause at least the stress part of the 3 ring circus, as i like to call it of many stress corrosion cracks scc in the aust. The stress corrosion cracking scc behaviour of medium carbon steel mcs in caustic soda, potash and a mixture of these reagents was studied by fracturing this material on a tensometer after every seven days of immersion in these media.
Effectively prevented by stress relieving heat treatment pwht a heat treatment at 1150f 621c is considered an effective stress relieving heat treatment. The material is not corrosion proof, but useful in certain cases. Picture for 04555 caustic stress corrosion cracking of. Stainless steel grades, such as the 304 or 316 types are generally suitable for storing and handling cold or unheated drinking towns waters. The material presented in this reference book has been.
The higher alloyed duplex stainless steel alloys, ones with significant molybdenum and nitrogen additions, can be superior to 316 ss in caustic environments. Mixed acids there is usually no appreciable attack on type 304 or 316 as long as sufficient nitric. The advantageous effect of nickel on limiting the stress corrosion cracking in boiling 42% mgcl2 is observed. Nickel and nickel base alloys are normally resistant to chloride stress corrosion cracking as compared to stainless steels. Caustic stress corrosion cracking of inconel600, incoloy800, and. Stress corrosion cracking scc results from the combined action of three factors. Stress corrosion cracking is a major issue for rcs system pipes particularly in the weld regions where it is connected to rpv nozzles through safe ends. Cracking was mainly transgranular with sections of intergranular branching. The susceptibility of austenitic stainless steel to stress. A case study on caustic corrosion in refinery piping.
It is one of the most prevalent afflictions in the industry and one of many environmental cracking mechanisms that typically occur in carbon steel equipment, but it can also afflict low alloy and austenitic stainless steel. Stress corrosion cracking of duplex stainless steels in. Stress corrosion cracking behavior of nickel base alloys. Certain austenitic stainless steels and aluminium alloys crack in the presence of chlorides. In 300 series ss cracking is typically transgranular through grains and very difficult to distinguish between chloride stress corrosion cracking. The ductility of type 304 austenitic stainless steel decreased with increased exposure time and concentration, an indication that it is susceptible to stress corrosion cracking in nacl. Causes of stress corrosion cracking scc in searching for the underlying causes that trigger scc, three basic mechanisms have been identified. High performance stainless steels stainless steel world. However, many dss grades have been reported to undergo corrosion and stress corrosion cracking in some aggressive environments such as chlorides and sulfidecontaining caustic. Pitting corrosion evaluation of austenitic stainless steel type 304 in acid. Variant sources of chloride induced stress corrosion cracking type 304 stainless steel 11th middle east corrosion conferencebahrain, 2006 2006. Caustic cracking in a 304l stainless steel pipe in methanol reforming service oxalic contact us if you have questions or need our depth of experience to help with your issues. Polythionic acid stress corrosion cracking pascc is a type of intergranular stress corrosion that affects sensitized stainless steels in refineries processing feedstocks containing sulphur.
The important general point is that those environments that cause stress corrosion are frequently highly specific to the particular. The impact of scc on a material usually falls between dry cracking and the fatigue threshold of that material. Thus, the addition of caustic soda to boiler feed waters to reduce the corrosiveness of the latter towards mild steel can result in the form of stress corrosion frequently referred to as caustic cracking. Immersion test was conducted at room temperature using ubend specimens. However, above approximately 121c, austenitic stainless steels, 304 particularly, are susceptible to stress corrosion cracking scc 2. There is an additional risk of stress corrosion cracking scc at higher temperatures. It is a broadly studied material for its immunity in stress corrosion cracking in warm water and caustic media. The use of material susceptible to stress corrosion cracking scc.
The stress corrosion cracking scc of sus 304 and sus 316 austenitic stainless steels at 353k in 0. Usually, economics dictate the use of materials that will corrode, but at an acceptable rate, in the given service. Resistance to caustics is generally in direct proportion to nickel content. The downcomer of an incinerator suffered sever cracking and loss of quenching water. Atmospheric stress corrosion cracking susceptibility. During this type of cracking,the metal is virtually unattacked over most of the surface while fine cracks progress through it at the attack site. Grades 2205 and 2906 are reported to have useful caustic cracking resistance.
Thus, an understanding of the factors that may lead to such scenario may help in extending the service life of the incinerator components. The effect of shot peening on the stress corrosion cracking. Selection of stainless steels for water tank applications. The prevalent theory of caustic scc indicates cracking of type304 stainless. The required tensile stresses may be in the form of directly applied stresses or in the form of residual. Stress corrosion cracking of sus 304 and sus 316 austenitic.
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